Magnesium (Mg), along with calcium and sulfur, is one of the three secondary nutrients required by plants for normal, healthy growth. Don’t be confused by the term "secondary" as it refers to the quantity and not the importance of a nutrient. A lack of a secondary nutrient is just as detrimental to plant growth as a deficiency of any one of the three primary nutrients (nitrogen, phosphorus and potassium) or a deficiency of micronutrients (iron, manganese, boron, zinc, copper and molybdenum). Furthermore, in some plants, the tissue concentration of magnesium is comparable to that of phosphorus, a primary nutrient.
Function of magnesium
Many enzymes in plant cells require magnesium in order to perform properly. However, the most important role of magnesium is as the central atom in the chlorophyll molecule. Chlorophyll is the pigment that gives plants their green color and carries out the process of photosynthesis. It also aids in the activation of many plant enzymes needed for growth and contributes to protein synthesis.
Deficiency:
Magnesium is mobile within the plant so deficiency symptoms appear first in older leaves. The symptoms show up as yellow leaves with green veins (i.e. interveinal chlorosis). Magnesium availability is not significantly affected by the pH of a soilless growing medium. However, it does become more available for plant uptake as the pH of the growing medium increases. Magnesium deficiency often is caused by lack of application, but it can be induced if there are high levels of calcium, potassium or sodium in the growing medium.